What is a primary battery? Provide a note on primary batteries and a note on dry cells.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) primary battery is a type of electrochemical cell in which the chemical reaction occurs only once. After use over a period of time,the reactants are consumed,the battery becomes dead,and it cannot be recharged or reused.
Dry Cell (Leclanché Cell):
It is the most common example of a primary battery.
Uses: It is commonly used in transistors,toys,and clocks.
Construction:
Anode: The cell consists of a zinc container that acts as the anode.
Cathode: The cathode is a carbon (graphite) rod,which is placed vertically in the center of the zinc cylinder.
Electrolyte: The space between the electrodes is filled with a moist paste of ammonium chloride $(NH_{4}Cl)$ and zinc chloride $(ZnCl_{2})$. The carbon rod is surrounded by a mixture of powdered manganese dioxide $(MnO_{2})$ and carbon.
Reactions:
Oxidation at the anode:
$Zn_{(s)} \rightarrow Zn^{2+} + 2e^{-}$
Reduction at the cathode:
$MnO_{2} + NH_{4}^{+} + e^{-} \rightarrow MnO(OH) + NH_{3}$
The $Zn^{2+}$ ions produced react with $NH_{3}$ to form a complex,$[Zn(NH_{3})_{4}]^{2+}$.
Overall cell reaction:
$Zn_{(s)} + 2MnO_{2} + 2NH_{4}^{+} \rightarrow Zn^{2+} + 2MnO(OH) + 2NH_{3}$
Cell potential: The potential of this cell is approximately $1.5 \ V$.

Explore More

Similar Questions

Which of the following acts as an oxidising agent in a hydrogen-oxygen fuel cell?

Standard electrode potentials for a few half cells are mentioned below:
$E^0_{Cu^{2+}/Cu} = 0.34 \ V, E^0_{Zn^{2+}/Zn} = -0.76 \ V$
$E^0_{Ag^{+}/Ag} = 0.80 \ V, E^0_{Mg^{2+}/Mg} = -2.37 \ V$
Which one of the following cells gives the most negative value of $\Delta G^0$?

The standard cell potential $(E_{\text{cell}}^{\ominus})$ of a fuel cell based on the oxidation of methanol in air that has been used to power television relay station is measured as $1.21 \ V$. The standard half-cell reduction potential for $O_2$ $(E_{O_2 / H_2 O}^0)$ is $1.229 \ V$. Choose the correct statement:

Depict the galvanic cell in which the reaction $Zn_{(s)} + 2Ag^{+}_{(aq)} \rightarrow Zn^{2+}_{(aq)} + 2Ag_{(s)}$ takes place,further show:
$(i)$ which of the electrode is negatively charged,
$(ii)$ the carriers of the current in the cell,and
$(iii)$ individual reaction at each electrode.

The chemical reaction taking place at the anode of a cell is

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo